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Steels can be
classified by a variety of different systems depending on:
The composition, such as carbon, low-alloy
or stainless steel.
The manufacturing methods, such as open hearth, basic oxygen process,
or electric furnace methods.
The finishing method, such as hot rolling or cold rolling
The product form, such as bar plate, sheet, strip, tubing or structural
shape
The deoxidation practice, such as killed, semi-killed, capped
or rimmed steel
The microstructure, such as ferritic, pearlitic and martensitic
The required strength level, as specified in ASTM standards
The heat treatment, such as annealing, quenching and tempering,
and thermomechanical processing
Quality descriptors, such as forging quality and commercial quality.

Carbon Steels
The American Iron and Steel Institute (AISI) defines carbon steel
as follows:
Steel is considered to be carbon steel when no minimum content
is specified or required for chromium, cobalt, columbium [niobium],
molybdenum, nickel, titanium, tungsten, vanadium or zirconium,
or any other element to be added to obtain a desired alloying
effect; when the specified minimum for copper does not exceed
0.40 per cent; or when the maximum content specified for any of
the following elements does not exceed the percentages noted:
manganese 1.65, silicon 0.60, copper 0.60.
Carbon steel can be classified, according
to various deoxidation practices, as rimmed, capped, semi-killed,
or killed steel. Deoxidation practice and the steelmaking process
will have an effect on the properties of the steel. However, variations
in carbon have the greatest effect on mechanical properties, with
increasing carbon content leading to increased hardness and strength.
As such, carbon steels are generally categorized according to
their carbon content. Generally speaking, carbon steels contain
up to 2% total alloying elements and can be subdivided into low-carbon
steels, medium-carbon steels, high-carbon steels, and ultrahigh-carbon
steels; each of these designations is discussed below.
As a group, carbon steels are by far
the most frequently used steels. More than 85% of the steel produced
and shipped in the United States is carbon steel.
Low-carbon steels contain up to 0.30%
C. The largest category of this class of steel is flat-rolled
products (sheet or strip), usually in the cold-rolled and annealed
condition. The carbon content for these high-formability steels
is very low, less than 0.10% C, with up to 0.4% Mn. Typical uses
are in automobile body panels, tin plate, and wire products.
For rolled steel structural plates
and sections, the carbon content may be increased to approximately
0.30%, with higher manganese content up to 1.5%. These materials
may be used for stampings, forgings, seamless tubes, and boiler
plate.
Medium-carbon steels are similar to
low-carbon steels except that the carbon ranges from 0.30 to 0.60%
and the manganese from 0.60 to 1.65%. Increasing the carbon content
to approximately 0.5% with an accompanying increase in manganese
allows medium carbon steels to be used in the quenched and tempered
condition. The uses of medium carbon-manganese steels include
shafts, axles, gears, crankshafts, couplings and forgings. Steels
in the 0.40 to 0.60% C range are also used for rails, railway
wheels and rail axles.
High-carbon steels contain from 0.60
to 1.00% C with manganese contents ranging from 0.30 to 0.90%.
High-carbon steels are used for spring materials and high-strength
wires.
Ultrahigh-carbon steels are experimental
alloys containing 1.25 to 2.0% C. These steels are thermomechanically
processed to produce microstructures that consist of ultrafine,
equiaxed grains of spherical, discontinuous proeutectoid carbide
particles.
High-Strength Low-Alloy Steels
High-strength low-alloy (HSLA) steels, or microalloyed steels,
are designed to provide better mechanical properties and/or greater
resistance to atmospheric corrosion than conventional carbon steels
in the normal sense because they are designed to meet specific
mechanical properties rather than a chemical composition.
The HSLA steels have low carbon contents (0.05-0.25% C) in order
to produce adequate formability and weldability, and they have
manganese contents up to 2.0%. Small quantities of chromium, nickel,
molybdenum, copper, nitrogen, vanadium, niobium, titanium and
zirconium are used in various combinations.
HSLA Classification:
Weathering steels, designated to exhibit
superior atmospheric corrosion resistance
Control-rolled steels, hot rolled according to a predetermined
rolling schedule, designed to develop a highly deformed austenite
structure that will transform to a very fine equiaxed ferrite
structure on cooling
Pearlite-reduced steels, strengthened by very fine-grain ferrite
and precipitation hardening but with low carbon content and therefore
little or no pearlite in the microstructure
Microalloyed steels, with very small additions of such elements
as niobium, vanadium, and/or titanium for refinement of grain
size and/or precipitation hardening
Acicular ferrite steel, very low carbon steels with sufficient
hardenability to transform on cooling to a very fine high-strength
acicular ferrite structure rather than the usual polygonal ferrite
structure
Dual-phase steels, processed to a micro-structure of ferrite containing
small uniformly distributed regions of high-carbon martensite,
resulting in a product with low yield strength and a high rate
of work hardening, thus providing a high-strength steel of superior
formability.
The various types of HSLA steels may also have small additions
of calcium, rare earth elements, or zirconium for sulfide inclusion
shape control.
Low-alloy Steels
Low-alloy steels constitute a category of ferrous materials that
exhibit mechanical properties superior to plain carbon steels
as the result of additions of alloying elements such as nickel,
chromium, and molybdenum. Total alloy content can range from 2.07%
up to levels just below that of stainless steels, which contain
a minimum of 10% Cr.
For many low-alloy steels, the primary function of the alloying
elements is to increase hardenability in order to optimize mechanical
properties and toughness after heat treatment. In some cases,
however, alloy additions are used to reduce environmental degradation
under certain specified service conditions.
As with steels in general, low-alloy
steels can be classified according to:
Chemical composition, such as nickel
steels, nickel-chromium steels, molybdenum steels, chromium-molybdenum
steels
Heat treatment, such as quenched and tempered, normalized and
tempered, annealed.
Because of the wide variety of chemical compositions possible
and the fact that some steels are used in more than one heat-treated,
condition, some overlap exists among the alloy steel classifications.
In this article, four major groups of alloy steels are addressed:
(1) low-carbon quenched and tempered (QT) steels, (2) medium-carbon
ultrahigh-strength steels, (3) bearing steels, and (4) heat-resistant
chromium-molybdenum steels.
Low-carbon quenched and tempered steels
combine high yield strength (from 350 to 1035 MPa) and high tensile
strength with good notch toughness, ductility, corrosion resistance,
or weldability. The various steels have different combinations
of these characteristics based on their intended applications.
However, a few steels, such as HY-80 and HY-100, are covered by
military specifications. The steels listed are used primarily
as plate. Some of these steels, as well as other, similar steels,
are produced as forgings or castings.
Medium-carbon ultrahigh-strength steels
are structural steels with yield strengths that can exceed 1380
MPa. Many of these steels are covered by SAE/AISI designations
or are proprietary compositions. Product forms include billet,
bar, rod, forgings, sheet, tubing, and welding wire.
Bearing steels used for ball and roller
bearing applications are comprised of low carbon (0.10 to 0.20%
C) case-hardened steels and high carbon (-1.0% C) through-hardened
steels. Many of these steels are covered by SAE/AISI designations.
Chromium-molybdenum heat-resistant
steels contain 0.5 to 9% Cr and 0.5 to 1.0% Mo. The carbon content
is usually below 0.2%. The chromium provides improved oxidation
and corrosion resistance, and the molybdenum increases strength
at elevated temperatures. They are generally supplied in the normalized
and tempered, quenched and tempered or annealed condition. Chromium-molybdenum
steels are widely used in the oil and gas industries and in fossil
fuel and nuclear power plants.
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